Research of the tribochemical system «bronze - organic additive - oil I-20A - steel».

  • О.А. Гордієнко
  • Т.С. Тітов
  • А.П. Ранський
  • О.В. Диха

Abstract

In this work was explored the tribochemical system «bronze – organic additive – oil I-20A – steel» in terms of the formation of coordination compounds of copper (II) under mechanical activation of metal surfaces of friction pair and or-ganic additives. It was found that lubricant compositions contained organic solvents with high donor value DNSbCl5, in fric-tion pair «bronze – steel» had the best anti-wear properties, which clearly points to the crucial role of donor activity of or-ganic aprotic solvents during oxidation of metals. Herewith the decisive influence of donor activity of organic solvents as a part of lubricating compositions on wear remained unchanged regardless of the contact pressure in the studied friction pair, and a significant improvement of tribotechnical performance of lubricant compositions contained organic additives compared to «pure» oil I-20A depended on the electron-donor (DNSbCl5) and adsorption (Ir) activity of the studied organic additives. Key words: organic additives, tribochemical system, coordination compounds of copper (II), electron-donor activity, adsorption activity.

References

1. Ranskiy A. P., Bojchenko P. V., Gordienko O. A., Didenko N. O., Voloshinec' V. A. Kompozycijni mastyl'ni materialy na osnovi tioamidiv ta i'h kompleksnyh spoluk. Syntez. Doslidzhennja. Vykorystannja, Vinnycja, VNTU, 2012, 328 p.
2. Ranskiy A. P., Gordienko O. A. Doslidzhennja prysadnyh materialiv na osnovi trygalogenpohidnyh karbonovyh kyslot v olyvi Y-40, Problemy trybologii', 2012, № 1, P. 55–61.
3. Ranskiy Anatolij Petrovych. Koordynacijni spoluky dejakyh 3d-metaliv z aromatychnymy ta geterocyklichnymy tioamidamy : dyp. … dokt. him. nauk : 02.00.01, Dnipropetrovs'k, 2003, 327 p.
4. Ranskiy A. P., Didenko N. O., Titov T. P., Bezvozjuk I. I. Mehanizm vybirkovogo perenesennja z tochky zoru rezonansnogo potencialu za Nechajevym [elektronnyj resurs], Naukovi praci Vinnyc'kogo nacional'nogo tehnichnogo universytetu, 2010, № 4, 4 p. https://praci.vntu.edu.ua/index.php/praci/article/view/230/228.
5. Jur'ev Ju. K. Prakticheskie raboty po organicheskoj himii. Izdanie 2-e, dop., М., Iz-vo Moskovskogo univer-siteta, 1961, Vyp. 1 i 2., 420 p.
6. Skopenko V. V., Garnovskij A. D., Kokozej V. N., Kuzharov A. P., Gohon- Zorilla G. Prjamoj sintez koor-dinacionnyh soedinenij, К., Venturi, 1997, 172 p.
7. Garnovskij A. D., Rjabuhin Ju. I., Kuzharov A. P. Prjamoj sintez koordinacionnyh soedinenij iz metallov v nevodnyh sredah, Koordinacionnaja himija, 1984, Т. 10, № 8, P. 1011–1033.
8. Maslennikov Stanislav Vladimirovich. Okislenie metallov organicheskimi soedinenijami v aprotonnyh rast-voriteljah : dip. … dokt. him. nauk : 02.00.08, 02.00.04, Nizhnij Novgorod, 2005, 201 p.
9. Maslennikov P. V., Spirina I. V., Piskunov A. V., Maslennikova P. N. Rol' rastvoritelja v sinteze metalloor-ganicheskih i metallosoderzhashhih soedinenij prjamym okisleniem metallov, Zhurnal obshhej himii, 2001, T. 71, Vyp. 11, P. 1837–1838.
10. Panteleev P. V., Maslennikov P. V., Egorochkin A. N., Vakulenko V. Ju. Vlijanie prirody rastvoritelja na skorost' okislenija metallov v aprotonnyh sredah, Zhurnal obshhej himii, 2001, T. 77, Vyp. 6, P. 912–916.
11. Panteleev P. V., Maslennikov P. V., Egorochkin A. N., Spirina I. V. Korreljacija reakcionnoj sposobnosti jelementoorganicheskih hloridov v reakcii okislenija metallov v aprotonnyh sredah, Zhurnal obshhej himii, 2007, T. 77, Vyp. 7, P. 1072–1074.
12. Kuprin Vitalij Pavlovich. Izbiratel'naja adsorbcija organicheskih veshhestv na metallah i podgotovka poverhnosti pered naneseniem pokrytij : dip. … dokt. him. nauk : 02.00.05, Dnepropetrovsk, 1993, 323 p.
13. Kuprin V. P., Shherbakov A. B. Adsorbcija organicheskih soedinenij na tverdoj poverhnosti, Kiev, Naukova dumka, 1996, 162 p.
14. Bovykin B. A., Ploshenko I. G., Ranskiy A. P., Mitrohin A. A. , Shtan'ko A. Ja., Suhovoj P. P. , Sedleckij V. D. A. p. 1409643 А1 SSSR, MKI С07М141/08 . Smazochnaja kompozicija, zajavl. 26.02.1986, opubl. 15.07.1988, Bjul. № 26.
15. Matjuhova Svetlana Alekseevna. Reakcii benzilgalogenidov s med'ju v dipoljarnyh aprotonnyh rastvoriteljah : dip. … kand. him. nauk : 02.00.03, Moskva, 2005, 185 p.
16. Ponomarenko A. G., Chigarenko G. G., Berchan G. P. O mehanizme obrazovanija polimerov trenija v smazochnyh maslah, Trenie i iznos, 1981, № 9, P. 43–45.
17. Garkunov D. N., Lozovskij V. N., Poljakov A. A. O mehanizme vzaimnogo atomnogo perenosa medi pri trenii bronzy po stali, Dokl. AN SSSR, 1960, T. 133, № 5, P. 1128–1129.
18. Spravochnik po tribotehnike. Teoreticheskie osnovy / Pod red. M. Hebdy, A. V. Chichinadze, M., Mashi-nostroenie, 1989, T. 1, 400 p.
19. Kuzharov A.P., Chuvaev V.V., Merinov B.V., Suchkov V.V., Kudrjavcev V.I. Issledovanie struktury granichnogo sloja i vlijanija kompleksoobrazujushhih prisadok na tribotehnicheskie svojstva pary trenija mednyj splav – stal', Trenie i iznos, 1987, T.8, №5, P. 851–856.
20. Barchan G. P., Chigarenko G. G, Ponomarenko A. G. Issledovanie izbiratel'nogo perenosa v srede slozhnyh jefirov monokarbonovyh kislot, Himija i tehnologija topliv i masel, 1978, № 10, P. 59–61.
21. Barchan G. P., Chigarenko G. G, Ponomarenko A. G. Vlijanie stroenija slozhnyh jefirov na process izbi-ratel'nogo perenosa, Himija i tehnologija topliv i masel, 1979, № 7, P. 36–39.
22. Pal'm V. A. Osnovy kolichestvennoj teorii organicheskih reakcij, L., Himija, 1977, 360 p.
Published
2017-06-20
How to Cite
Гордієнко, О., Тітов, Т., Ранський, А., & Диха, О. (2017). Research of the tribochemical system «bronze - organic additive - oil I-20A - steel». Problems of Tribology, 84(2), 43-49. Retrieved from http://tribology.khnu.km.ua/index.php/ProbTrib/article/view/596
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Articles