Effect of fullerene-like nanoparticles at low concentrations on the anti-wear properties of motor fuels
DOI:
https://doi.org/10.31891/2079-1372-2022-104-2-49-54Keywords:
tribological characteristics of lubricants, motor fuels, antiwear additives, bearing capacity, fullerenes and fullerene-like nanoparticlesAbstract
Motor fuels are the source of energy for internal combustion engines, and also a lubricant for friction units of the fuel equipment of automobile, aircraft and ship engines. The reliability and service life of the entire mechanism depend on the antiwear properties of fuels. Traditional anti-wear additives containing sulfur, phosphorus, chlorine, etc., are not applicable in motor fuels due to restrictions on emissions of toxic compounds. To improve the antiwear properties of lubricants, it is possible to use a new class of spatial carbon compounds - fullerene-like nanoparticles (FLNs).
This work shows that modification of liquid hydrocarbon motor fuels with fullerene-like nanoparticles (FLNs) increases the antiwear properties of fuels
References
2. Likhterova N.M., Seleznev M.V., Goryunova A.K. Tribologicheskiye kharakteristiki sovremennykh aviatsionnykh kerosinov. Neftepererabotka i neftekhimiya. 2019. № 7. S. 35–40.
3. Zhang J., Spikes H. On the Mechanism of ZDDP Antiwear Film Formation. Tribol. Lett. 2016. V. 63. P. 3–27.
4. Rastogi R.B., Maurya J.L., Jaiswal V. Phosphorous free antiwear formulations: zinc thiosemicarbazones–borate ester mixtures. Proc. IMechE, Part J: J Engineering Tribology. 2012. V. 227. P. 220–233.
5. The technical regulations for automobile gasoline, diesel, ship and boiler fuels. Cabinet of Ministers of Ukraine, 2013, 22p.
6. Lyubchuk T.V. Fulereny ta inshi aromatychni poverkhni (struktura, stabilʹnistʹ, shlyakhy utvorennya). K.: Vydavnycho-polihrafichnyy tsentr “Kyyivsʹkyy universytet”. 2005. 322 s.
7. Tuktarov A.R., Khuzin A.A., Dzhemilev U.M. Fullerenosoderzhashchiye smazochnyye materialy: dostizheniya i perspektivy (obzor). Neftekhimiya. 2020. T. 60, № 1. S. 125–147.
8. Yeletskiy A.V. Fullereny v rastvorakh. Teplofizika vysokikh temperatur. 1996. T. 34, № 2. S. 308–323.
9. Ginzburg B.M., Baydakova M.V., Kireyenko O.F., Tochil'nikov D.G., Shepelevskiy A.A. Vliyaniye fullerena C60, fullerenovykh sazh i drugikh uglerodnykh materialov na granichnoye treniye skol'zheniya metallov. Zhurnal tekhnicheskoy fiziki. 2000. T. 70, Vyp. 12. S. 87–97.
10. Kravtsov A.G. Modelirovaniye formirovaniya maslyanoy plenki na poverkhnosti treniya pri nalichii fullerenovykh dobavok v smazochnom materiale i yeye vliyaniye na skorost' iznashivaniya tribosistem. Problems of Tribology. 2018. № 1. S. 69–77.
11. Polunkin YE.V., Pylyavsʹkyy V.S., Bereznytsʹkyy YA.O., Kamenyeva T.M., Levterov A.M., Avramenko A.M. Pokrashchennya khimmotolohichnykh vlastyvostey dyzelʹnoho palyva mikrodobavkoyu vuhletsevykh sferoyidalʹnykh nanochastok. Kataliz ta naftokhimiya. 2020. №. 29. S. 59–64.
12. Increasing surface wear resistance of engines by nanosized carbohydrate clusters when using ethanol motor fuels / O.O. Haiday, V.S. Pyliavsky, Y.V. Polunkin, Y.O. Bereznytsky, O.B. Yanchenko, A. Smolarz, P. Droździel, S. Amirgaliyeva, and S. Rakhmetullina. Mechatronic Systems 1. London, 2021. P.89-99. URL: https://doi.org/10.1201/9781003224136-8
13. Rud' A.D., Kuskova N.I., Boguslavskiy L.Z., Kir'yan I.M., Zelinskaya G.M., Belyy N.M. Strukturno-energeticheskiye aspekty sinteza uglerodnykh nanomaterialov vysokovol'tnymi elektrorazryadnymi metodami. Khimiya i khimicheskaya tekhnologiya. 2013. T. 56, Vyp. 7. S. 99–104.
14. Yadav G., Tiwari S., Jain M.L. Tribological analysis of extreme pressure and anti-wear properties of engine lubricating oil using four ball tester. Materials Today. 2018. V. 5, No. 1. Part 1. P. 248–253.